The cover price is US$30.00. This book contains 122 pages.
Typical
Aerial Shell Firing Time Sequence |
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As part of a continuing study of the nature and causes of aerial
shell malfunctions, it was useful to produce a detailed time sequence
for the events occurring during the firing of typical (properly functioning)
aerial shells. While it is recognized that few if any non-researchers
will find much practical information in this article, it was written
in the thought that such information might be of general interest
to those wishing to better understand the shell firing process. The
information used in preparing this time sequence of shell firing events
comes from several sources, some of which has been published previously.
The sources of information include normal and high frame rate video
recording of aerial shell firings, mortar pressure profiles (internal
mortar pressure as a function of time) during actual shell firings,
and simple calculations based Newton's second law of motion. |
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Confirmation
of Mortar Recoil Information |
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An earlier article presented information about the magnitude
of firework mortar recoil forces. As a starting point, that article
used the averages of 136 measurements of the peak internal mortar
pressure produced upon firing 3- to 12-inch spherical aerial shells.
These peak pressures were then converted to recoil forces using
basic principles of physics. However, while the average peak recoil
force results are thought to be highly reliable for typical shells,
those results were not confirmed by physical measurements of peak
recoil forces.
During the 1990s, the Canadian Explosives Research Laboratory (CERL)
conducted a large number of measurements of firework mortar recoil
forces. Some of the results from the testing of 205-, 255- and 305-millimeter
(8-, 10-, and 12-inch) aerial shells have been published. Approximately
half of these test shells were produced in the Orient and half were
from Europe. The purpose of this short article is to compare the
CERL results with the results the earlier article and to draw some
conclusions from those comparisons. |
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Angelfire
Brand of Indoor Pyrotechnics |
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Recently, a supply of indoor (proximate audience) pyrotechnic items
was supplied for our casual (non-quantitative) evaluation. The claim
to fame for this product line is reputed to be its low smoke output
and its high purity flame colors. The principals of the company (DMD
Systems, LLC) are some of the same researchers that previously developed
and wrote about similarly performing pyrotechnics in the Journal of
Pyrotechnics. We were willing to provide such a cursory evaluation
(without cost) because of our general curiosity regarding these products. |
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Black
Powder Stability and Aging Example |
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The stability and aging characteristics of Black Powder
are occasional topics of discussion. Having been given a research
sample of Black Powder that had been recovered from the explosive
charge in cannon balls dating to the time of the US Civil War (ca.
1863), the author was able to investigate these issues for that powder
sample. |
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Another
Example of Explosively Malfunctioning Comets |
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This article reports on another batch of comets, imported from
China, that tend to malfunction by exploding violently within their
mortars as they are being fired. In the last few years, the authors
have reported on imported Chinese comets from two other manufacturers,
with somewhat similar construction characteristics, that also tended
to explode violently upon their firing.[2-6] In each case, it was
found that the malfunctioning white (or silver) comets had a high
percentage of very fine magnalium (magnesium-aluminum alloy), used
potassium perchlorate as the oxidizer, and had internal voids that
could function as fire paths.
The comets in question for this article are of two different types:
3-inch solid cylindrical comets, and 3-inch tiger tail comets made
by layering comet composition over an internal aerial shell.[1]
While some cartons of both types of comets tended to experience
the same explosive malfunctions, only the cylindrical comets were
carefully studied and will be discussed in this article. |
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Primer
Gunshot Residue Detection from the Firing of a Black Powder Revolver |
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A study was conducted to determine the potential for being able
to identify primer gunshot residue (PGSR) within the substantial quantities
of the particulate residues produced during the firing of a revolver
using Black Powder propellant and a percussion cap primer. Samples
of gunshot residue (GSR) were collected from the shooter’s hands,
from surfaces to the side of the shooter, from surfaces near the muzzle
of the weapon and from various locations on the weapon itself (both
inside and outside). It was found to be relatively easy to identify
PGSR from the hand of the shooter, from surfaces to the side of the
weapon and from most locations on the weapon. However, using the methods
of this study, no PGSR was identified within the large amount of Black
Powder residue projected out the muzzle of the weapon and on the inside
of its barrel. |
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Keywords: gunshot residue, GSR,
Black Powder, percussion cap primer, scanning electron microscopy,
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Air
Blast TNT Equivalency for Rolls of Paper Toy Caps |
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A study of the explosive output of rolls of paper toy caps, in variously
sized assemblages, was conducted. The testing has shown that toy cap
rolls are clearly capable of producing a powerful explosive effect
if initiated with a sufficiently energetic event. TNT equivalencies
based on toy cap composition mass ranged from approximately 10 to
80% for different sized configurations, with the largest equivalences
being produced by the largest assemblages of toy caps tested. The
results of this study are disturbing, considering that the toy caps
(even in bulk packaging) have a UN classification of Explosive1.4S,
which by definition should not produce significant blast or fireball
effects when initiated. Thus perhaps it is appropriate to consider
whether the UN test protocol is adequate for this product. |
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Keywords: air blast, TNT equivalence,
toy caps, Armstrong’s mixture, UN test Reprint
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Mortar
Plug and Recoil Problems |
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As is so often the case, this is an instance where one might take
a useful lesson from someone else's unfortunate experience. This article
recounts a relatively minor incident experienced by a display company,
but one that could have been of significantly greater consequence.
The purpose of the article is to use this incident as the basis for
discussing potential problems regarding mortar plug attachment and
mortar recoil forces, which others in the industry may benefit from
considering in greater detail. |
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Avoiding
Making Comets That Explosively Malfunction |
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In recent years, there have been at least three separate instances
where white (or silver) comets, which were manufactured in China,
have demonstrated a tendency to malfunction by powerfully exploding
when they are fired. In each instance, the comets were solid masses
of composition, as opposed to being crossettes or some other type
of intentionally exploding comets. In studying these comets, even
though there were three different types of comet devices under three
different brand names, it was discovered that they shared some characteristics
in common that understandably account for their explosive malfunctions.
After providing a limited amount of background information, it is
the purpose of this article to identify the problem characteristics
and to recommend an easy and cost effective means for manufacturers
to avoid similar malfunctions in the future. |
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Lessons
from a Fatal Accident |
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There was a fatal accident not too long ago while a worker was preparing
aerial shells for use in a firework display. What makes a discussion
of this accident particularly relevant is that it involved: a) a smaller
amount of pyrotechnic material than is often worked with at display
companies, b) materials that were significantly less explosive than
are often worked with at display companies, and c) a number of work
practices that are somewhat common at many display companies. It is
hoped that a discussion of this accident may help to identify some
work practices and work facilities that should be considered for improvement
from the standpoint of worker safety. |
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Initial
Tests of Barge Safety Shelter Resistance to Penetration by Aerial
Shells |
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In the 2000 edition of the National Fire Protection
Association's Code for Fireworks Display, a chapter was added with
requirements for performing displays on barges and floating platforms.
One of those requirements for manned displays when fired electrically
(or as an alternative fired manually) is to provide a safety shelter
for the on-board crew. (In the 2006 edition of the code, a safety
shelter is also required for roof-top and limited-access displays,
unless the electrical firing crew is located at least 75 feet from
the nearest mortar.)
One requirement for the construction of the safety shelter is that
it be made using at least the equivalent of 3/4-inch plywood. While
it might reasonably be concluded that some number of standard dimensional
2x4's would also be used in the construction that is not specified
in the NFPA code. One requirement for the placement of the safety
shelter is that it be placed at least 2 feet per inch of mortar
diameter away from mortars up to 6-inch in diameter and at least
4 feet per inch of mortar diameter away from mortars larger than
6-inch diameter.
In drafting the 2000 version of the code it was widely accepted
by the NFPA's Technical Committee on Pyrotechnics that a safety
shelter was a good idea and that the construction and placement
requirements were reasonable. However, at that time no one had any
test data to offer in support of the concept of a safety shelter,
its manner of construction, or its positioning with respect to the
mortars in the display. Thus, it seemed worthwhile to the authors
to conduct some testing of safety shelters. (Unfortunately, it has
taken several years for the authors to find the time to begin to
work on this project.) |
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Evaluation
of “Quick-Fire” Clips |
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Quick-Fire clips are a product of Martinez Specialties and come
in two varieties. One is the “VF” clip, which is primarily
intended to couple to and ignite visco-like fuse products using an
electric match. The other is the “LC” clip, which is primarily
intended to ignite the lift charge of aerial shells using an electric
match. (However, both clip types have other useful applications as
well.) Supplies of both types of Quick-Fire clips were provided by
Martinez Specialties for an evaluation of their effectiveness. This
article is a brief report of those product evaluations. |
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Thermodynamic and Spectroscopic
Analysis of a Simple Lilac Flame Composition |
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A simple lilac flame composition consisting of 80% potassium nitrate
and 20% shellac was investigated by emission spectroscopy and thermodynamic
modeling. The flame from the burning composition had a reddish-pink
core with a brighter pale lilac outer envelope. The core of the flame
is presumably close to the equilibrium conditions predicted by thermodynamic
modeling. The calculated equilibrium flame temperature is 1526 K;
seven gases (CO, H2O, N2, CO2, H2,
KOH, K) and one liquid (K2CO3) account for 99.7%
of the molecules in the core of the flame. Of these, liquid potassium
carbonate (mole fraction 9.6%) is expected to emit a continuous spectrum
while atomic potassium (mole fraction 2.5%) imparts a red colour from
the resonance doublet (766.491 and 769.897 nm), which is considerably
broadened by self-absorption. The outer flame envelope is presumably
a diffusion flame in which flammable gases from the core burn in entrained
air. The maximum adiabatic temperature of such a flame was calculated
as 1723 K; seven gases (N2, CO2, H2O,
KOH, K, Ar, K2O2H2) account for 99.8% of the molecules in the outer
flame envelope. The emission spectrum of atomic potassium superimposed
on a continuous spectrum arising from the combining of atomic potassium
with OH radicals to form gaseous KOH is responsible for the lilac
colour of laboratory flames containing potassium and is the likely
cause of the lilac colour of the outer regions of this pyrotechnic
flame. The article includes a brief tutorial outline of some relevant
aspects of the atomic spectroscopy of potassium. |
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Keywords: lilac flame colour,
potassium nitrate, shellac, thermodynamic modeling, visible spectrum
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Spark Travel Distance |
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It is generally recognized that spark particle size is one of the
factors controlling how far sparks will be propelled from various
firework items. However, there is relatively little quantitative information
in the pyrotechnic literature documenting the distance sparks travel
as a function of their initial size. This article reports on a brief
study of maximum titanium spark particle travel distance as a function
of the mesh size of sponge titanium included in two sizes of relatively
small flash powder salutes. |
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Further
Testing of NFPA Safety Shelters |
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Before describing this work it should be mentioned that the purpose
was not to find fault with the requirement of the National Fire Protection
Association (NFPA) in its Code for the Display of Fireworks
for a safety shelter on manned electrically fired displays on barges.
Rather, it is to determine the level of protection actually provided
by a shelter meeting the minimum NFPA requirement as it is most often
applied, to share that information with the industry, and to offer
suggestions to those that might wish a higher level of protection.
Probably the most extreme test of NFPA’s required barge safety
shelter construction is the direct impact of an aerial shell fired
from the minimum distance allowed. To begin this investigation,
last fall some initial testing was conducted and the results were
reported. In summary, when a typical 3-inch shell was fired directly
at the plywood (i.e., perpendicular to its front surface) from a
distance of 8 feet, the 3-inch shell was found to be capable of
penetrating ¾-inch AC exterior plywood backed with 2×4
dimensional lumber on 2-foot centers. Following this somewhat surprising
result, thought was given to relatively easy and inexpensive ways
that the shelter’s resistance to shell penetration might be
improved. During further trials, it was eventually found that relatively
simple and inexpensive modifications could be made that provided
substantially improved penetration resistance, ranging to at least
6-inch shells. Descriptions of many of the trials and their results
are presented below.
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Convenient Couplers for
Lightning Thermo-Tube |
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An earlier article addressed the characteristics and methods for
the use of Lightning Thermo-Tube™ (LTT). At about that time,
some inexpensive plastic components that can be used to facilitate
the coupling and branching of LTT were supplied for evaluation. This
article reports on a brief study of the effectiveness and utility
of those components. |
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An Evaluation of Lightning
ThermoTube™ as a Pyrotechnic Ignition System |
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Lightning Thermo Tube (LTT) is a recently introduced type of shock
tube with characteristics that make it suitable for use with common
pyrotechnics. LTT is reliably initiated by reasonably energetic electric
matches and reliably ignites most pyrotechnic compositions. LTT is
physically strong, easily spliced and branched, and is highly weather
resistant. LTT produces a moderately bright flash of light upon functioning,
which may be a useful effect in itself. This paper presents the results
of a series of tests performed to determine some of the more important
capabilities and characteristics of LTT as it relates to use with
pyrotechnics in general and fireworks in particular. |
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Probabilities
of Dying from Various Causes |
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In the August 2006 issue of the National Geographic,
S. Roth published a comparison of probabilities of Americans dying
from various causes, based on 2003 data from the National Safety Council.
The data provides some interesting information that helps to keep
things in perspective when attempting to evaluate some of the risks
associated with life. |
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A
Study Evaluating the Potential for Various Aluminum metal Powders
To Make Exploding Fireworks |
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This investigation was commissioned to evaluate a range of various
aluminum metal powders for their potential use in compounding flash
powders for use in powerfully exploding devices such as so-called
M-80s and devices of similar construction. |
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Forensic
Accident Investigation using Pyrotechnic Residue Particle Analysis |
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Pyrotechnic reaction residue particle (PRRP) production, sampling
and their basic analyses are similar to that for primer gunshot residue
(PGSR). Both types of particles originate from energetic chemical
reactions that generate products that are initially melted and/or
vaporized. These chemical reaction products are dispersed by the temporary
and permanent gases from the chemical reaction. Then the reaction
products solidify and are deposited as tiny spheroidal particles on
objects in the area. Sampling is accomplished using conductive carbon
adhesive dots. Analysis is performed using scanning electron microscopy
to locate potential PRRPs and energy dispersive X-ray spectroscopy
is used to characterize the signature of each suspect particle’s
constituent chemical elements. Often, standard micro-analytical
chemistry performed on pyrotechnic residues cannot be expected to
provide sufficient information for an investigation of the cause
and course of an accident. On those occasions, PRRP analysis generally
provides important information that is not otherwise available.
For example, there are times when standard micro-analytical chemistry
will fail to discriminate sufficiently between materials of pyrotechnic
origin and other unrelated substances also present on the items
being sampled. In addition, there are times when PRRP analysis can
help identify details concerning the cause and course of events
that are simply beyond the capability of micro-analytical chemistry.
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